Articles
Vol. 11 (2024)
The Research Progress on Photocatalytic Materials for Pollutant Degradation: A Review
School of Environmental and Municipal Engineering, Qingdao University of Technology, No. 777, Jialingjiang East Rd., Qingdao, 266520, P.R. China
School of Environmental and Municipal Engineering, Qingdao University of Technology, No. 777, Jialingjiang East Rd., Qingdao, 266520, P.R. China
"School of Environmental and Municipal Engineering, Qingdao University of Technology, No. 777, Jialingjiang East Rd., Qingdao, 266520, P.R. China" & "Key Lab of Industrial Fluid Energy Conservation and Pollution Control (Ministry of Education), Qingdao University of Technology"
School of Environmental and Municipal Engineering, Qingdao University of Technology, No. 777, Jialingjiang East Rd., Qingdao, 266520, P.R. China
Jimo Branch of Qingdao Ecological Environment Bureau, No. 146-1 Zhenhua Street, Jimo District, Qingdao City, Shandong Province
School of Environmental and Municipal Engineering, Qingdao University of Technology, No. 777, Jialingjiang East Rd., Qingdao, 266520, P.R. China
Abstract
Photocatalytic technology, as a clean, green, and sustainable method for pollutant degradation, has significant scientific research value and practical application significance in the field of water pollution control. Currently, the focus of photocatalysis research is on developing efficient, stable, and low-cost photocatalysts. Researchers are enhancing the light absorption capacity, electron-hole separation efficiency, and degradation rate of photocatalysts by designing novel photocatalysts, such as S-type heterojunctions, Z-scheme structures, precious metal doping, and non-metal regulation. The mechanistic study of the photocatalytic process, especially the separation, migration, and transfer mechanisms of photogenerated carriers, provides theoretical support for the optimization design of photocatalysts. At present, there are various types of catalysts for photocatalytic degradation of pollutants, including metal oxide catalysts (e.g., TiO2, ZnO), precious metal catalysts (e.g., platinum, gold, silver), carbon-based catalysts (e.g., graphene, carbon nanotubes), and composite catalysts (e.g., metal oxide-carbon-based composite catalysts).Each type of catalyst has shown performance in improving photocatalytic efficiency and expanding the light absorption range, but also faces challenges such as limited light absorption range, poor catalyst stability, and high cost. Composite catalysts significantly improve photocatalytic efficiency through synergistic effects, especially excelling in the degradation of high-concentration pollutants. Future research will focus on further optimizing the performance of catalysts, particularly expanding the light absorption range, improving electron-hole separation efficiency, and enhancing catalyst stability. The design of composite catalysts remains the focus of research, especially the exploration of synergistic effects between different materials. At the same time, issues such as the long-term stability, recyclability, and selectivity of catalysts need to be addressed to support their large-scale application.
References
- Hubbard R, Brown KP, Kropf A. Action of Light on Visual Pigments [J]. Nature, 1959, 183(4659): 442. https://doi.org/10.1038/183442a0
- Qi S, Jiang L, Bin W, et al. Direct Z-scheme Bi2MoO6/UiO-66-NH2 heterojunctions for enhanced photocatalytic degradation of ofloxacin and ciprofloxacin under visible light [J]. Applied Catalysis B: Environmental, 2022, 318. https://doi.org/10.1016/j.apcatb.2022.121820
- Zheng XY, et al. (2018). "Enhanced degradation of ciprofloxacin by graphitized mesoporous carbon (GMC)-TiO2 nanocomposite: Strong synergy of adsorption-photocatalysis and antibiotics degradation mechanism." Journal of Colloid and Interface Science 527: 202-213. https://doi.org/10.1016/j.jcis.2018.05.054
- Ahmed AAZ, Alenazi AN, Almotairy RA, et al. Remarkable recycling processes of conjugated polymers with titanium dioxide quantum dots as photocatalysts for photodegradation of hazardous industrial wastewater [J]. Results in Engineering, 2024, 24103412-103412.
- Zhikun L, Yifeng X, Lai P, et al. A two-stage degradation coupling photocatalysis to microalgae enhances the mineralization of enrofloxacin [J]. Chemosphere, 2022, 293133523-133523.
- Dong X, Hailing M. Degradation of rhodamine B in water by ultrasound-assisted TiO2 photocatalysis [J]. Journal of Cleaner Production, 2021, 313. https://doi.org/10.1016/j.jclepro.2021.127758
- González-Burciaga LA, et al. (2022). "Challenges of TiO2 heterogeneous photocatalysis on cytostatic compounds degradation: state of the art." Environmental Science and Pollution Research 29(28): 42251-42274. https://doi.org/10.1007/s11356-021-17241-8
- Wang X, Jia J, Wang Y. Combination of Photocatalysis with Hydrodynamic Cavitation for Degradation of Tetracycline [J]. Chemical Engineering Journal, 2017, 315274-282. https://doi.org/10.1016/j.cej.2017.01.011
- Zoltán Z, Orsolya F, Erzsébet S, et al. Degradation of industrial surfactants by photocatalysis combined with ozonation [J]. Environmental science and pollution research international, 2014, 21(19): 11126-34. https://doi.org/10.1007/s11356-014-2527-2
- Wang Q, Zhou W, Li C, et al. Construction of Bi2MoO6 sheets/NH2-UiO-66(Zr) hetero junction photocatalysts toward enhanced degradation of tetracycline under visible light [J]. Journal of Alloys and Compounds, 2025,1010177589-177589. https://doi.org/10.1016/j.jallcom.2024.177589
- Wu C, Zhang J, Wu Y, et al. Degradation of phenol in water by the combination of sonolysis and photocatalysis [J]. Desalination and Water Treatment, 2014, 52(10-12): 1911-1918. https://doi.org/10.1080/19443994.2013.795879
- Jin C, Wang C, Huang T, et al. Hollow amorphous N-doped TiO2 microspheres with uniform shell thickness and high carrier separation efficiency for photocatalytic of high-concentration Cr(VI) [J]. Optical Materials, 2025, 159116516-116516. https://doi.org/10.1016/j.optmat.2024.116516
- Yinghui Q, Zhenyu C, Yukuan D, et al. H2O2 assisted photocatalysis over Fe‐MOF modified BiOBr for degradation of RhB[J].Journal of Chemical Technology & Biotechnology, 2022, 97(10): 2881-2888. https://doi.org/10.1002/jctb.7199
- Li Y, Song J, Yang J, et al. A novel S-scheme heterojunction based on BiPO4/CdPSe3 for effective photocatalytic degradation of organic pollutants [J]. Journal of Alloys and Compounds, 2025, 1010177491-177491. https://doi.org/10.1016/j.jallcom.2024.177491
- 冯海东. 廉价金属掺杂TiO2光催化剂制备与性能研究[D]. 沈阳大学,2024.DOI:10.27692/d.cnki.gsydx.2024.000001.
- Gao WW, He PZ, Wang HY, et al. Enhanced persulfate-assisted photocatalytic degradation of phenol by Ag/ZnFe2O4 composite[J].Journal of Alloys and Compounds, 2025, 1010177578-177578. https://doi.org/10.1016/j.jallcom.2024.177578
- Wang Y, Zhang P, Li F, et al. H2O2-assisted Bi3NbO7 loaded on porous carbon for enhancing the photocatalytic degradation of tetracycline[J].Solid State Sciences, 2024, 158107763-107763. https://doi.org/10.1016/j.solidstatesciences.2024.107763
- Wang Y, Li M, Ding M, et al. Construction of Ag2Mo2O7-loaded graphdiyne S-scheme hetero junction for photocatalytically coupled peroxydisulfate -activated degradation of 2,4-dichlorophenol [J]. Chemical Engineering Journal, 2025, 503158196-158196. https://doi.org/10.1016/j.cej.2024.158196
- 王智远, 田伟光, 余伟, 等. 多孔异质结g-C3N4/TiO2光催化剂的制备及其光催化性能研究[J/OL].功能材料, 1-8[2024-12-22]. http: //kns.cnki. net/kcms/detail/ 50.1099 .th.20241204.1110.046.html.
- 郑佳红, 黄植. Fe3O4/CoS/g-C3N4 催化剂的制备及降解罗丹明B [J]. 硅酸盐学报, 2024, 52(12): 3748-3760. https://doi:10.14062/j.issn.0454-5648.20240461
- Wang R, Fu X, Guo Y, et al. WO3/g-C3N4 synergistic photocatalysts for degradation and H2 production [J]. Ceramics International, 2024, 50(24PC): 55714- 55725. https://doi.org/10.1016/j.ceramint.2024.10.442
- Wang H, Chu J, Ou H, et al. Analysis of TiO2 photocatalysis in a pulsed discharge system for phenol degradation [J]. Journal of Electrostatics, 2009; 67(6): 886-889. https://doi.org/10.1016/j.elstat.2009.07.008
- Mark C, Reece L, Cynthia G. Heterogeneous vs homogenous photocatalysis: what dominates in the degradation of methyl orange and methylene blue mixtures? [J]. Photochemical & photobiological sciences: Official journal of the European Photochemistry Association and the European Society for Photobiology, 2023, 22(6): 1463-1474. https://doi.org/10.1007/s43630-023-00390-9
- Maham, Muneer I, Cheema NA, et al. Hydrothermal synthesis of Gd-doped CaO nanoparticles from lemon peel extract for efficient photocatalytic degradation of methylene blue under UV and sunlight [J].Ceramics International,2024, 50(24PB): 54064-54075. https://doi.org/10.1016/j.ceramint.2024.10.264
- Eddy ON, Oladede J, Eze SI, et al. Synthesis and characterization of CaO nanoparticles from periwinkle shells for the treatment of tetracycline-contaminated water by adsorption and photocatalyzed degradation [J]. Results in Engineering, 2024, 24103374-103374. https://doi.org/10.1016/j.rineng.2024.103374
- SMH, Giridhar M, CKP. Noble metal ionic catalysts [J]. Accounts of chemical research, 2009, 42(6): 704-12. https://doi.org/10.1021/ar800209s
- Dal Santo, V. and A. Naldoni (2018). "Titanium Dioxide Photocatalysis." Catalysts 8(12). https://doi.org/10.3390/catal8120591
- Yang R, Lingjun K, Yiwen Z, et al. Review on the synthesis and activity of iron-based catalyst in catalytic oxidation of refractory organic pollutants in wastewater [J]. Journal of Cleaner Production, 2021, 321. https://doi.org/10.1016/j.jclepro.2021.128924